The vacancy was advertised online by the Belgian Football Association (BFA). It said it had wanted a “strong and open communicator” who has a “proven track record in transmitting tactical and strategic knowledge” to top players.
In a statement, the BFA said it was “delighted and proud to have found a coach at this level so quickly”.
Martinez’s first match is against Spain on September 1. At Everton, he managed Belgium internationals Marouane Fellaini, Romelu Lukaku and Kevin Mirallas.
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