Steph Houghton will captain a 23-strong squad which includes 11 World Cup debutantes, while Karen Carney and Jill Scott will head to a fourth tournament. Omitted were injured Izzy Christiansen and veteran Fara Williams.
Neville said: “I’m absolutely convinced we can have a successful tournament. We’ve got a squad that is highly motivated, that now has the confidence and belief to go to a World Cup to be successful. We keep saying it but the hard work starts now and we are going to give it everything we have to make the nation proud.”
England begin their campaign against Scotland on Sunday, 9 June, and will also face Argentina and 2011 champions Japan in the group stage.
Neville considered England, who finished third in 2015, as being in a “really difficult group” with “three dangerous teams”.
He added: “We are the third-ranked team in the world and there is a lot of expectation but our performances have been really good and there is more to come from these players.”
Chelsea playmaker Fran Kirby makes the final 23 despite missing recent friendlies against Canada and Spain because of a knee injury. Wolfsburg’s Mary Earps has been handed the third goalkeeper spot ahead of Manchester City’s Ellie Roebuck, however there is no place for US-born Orlando Pride forward Chioma Ubogagu.
Earps, Bright, Abbie McManus, Leah Williamson, Demi Stokes, Rachel Daly, Lucy Staniforth, Georgia Stanway, Keira Walsh, Nikita Parris and Beth Mead will all travel to their first World Cup.
The Lionesses revealed the squad earlier on Wednesday through a series of social media posts from high-profile supporters, including Prince William, former England men’s captain David Beckham and actress Emma Watson.
England squad
Goalkeepers: Karen Bardsley (Man City), Mary Earps (Wolfsburg), Carly Telford (Chelsea)
Defenders: Millie Bright (Chelsea), Lucy Bronze (Lyon), Rachel Daly (Houston Dash), Alex Greenwood (Man Utd), Steph Houghton (captain, Man City), Abbie McManus (Man City), Demi Stokes (Man City) Leah Williamson (Arsenal)
Midfielders: Karen Carney (Chelsea), Jade Moore (Reading), Jill Scott (Man City), Lucy Staniforth (Birmingham City), Georgia Stanway (Man City), Keira Walsh (Man City)
Forwards: Toni Duggan (Barcelona) Fran Kirby (Chelsea), Beth Mead (Arsenal), Nikita Parris (Man City), Jodie Taylor (Seattle Reign), Ellen White (Birmingham City)